Synthesis and Characterization of PEDOT: PSS-PAs with Good Electrical Conductivity for Supercapacitor
Long Shen
Department of Advanced Materials, Hannam University, Daejeon-305-811, Republic of Korea.
Yoon Kim
Department of Advanced Materials, Hannam University, Daejeon-305-811, Republic of Korea.
Dong-Ju Lee
Department of Advanced Material Engineering, Chungbuk National University, Chungju 28644, Republic of Korea.
Tae-Dong Kim *
Department of Advanced Materials, Hannam University, Daejeon-305-811, Republic of Korea.
*Author to whom correspondence should be addressed.
Abstract
Recently, researches on molecular engineering of PEDOT:PSS is being actively conducted to improve the electrical conductivity and device performance. In this paper, we prepared and characterized a series of PSS substituted with alkyl sulfonate (PSS-co-PA3, PSS-co-PA5, PSS-co-PA10, and PSS-co-PA30) proceeding to prepare PEDOT:PSS/graphene oxide (GO) aerogels with different amounts of alkyl sulfonate functional groups that could be applied to supercapacitor electrodes. The introduction of alkyl sulfonate groups in PSS can enhance its solubility due to the flexible alkyl sulfonate groups. The cycle stability of supercapacitors using PEDOT:PSS-co-PA30/rGO electrode (88%) was improved compared to that of Clevios 4083/rGO electrode (53%) after 5000 cycles.
Keywords: Conducting polymers, PEDOT:PSS-PAs, graphene oxide, supercapacitor, electrical conductivity
How to Cite
Downloads
References
Liu D, Chen LC, Liu T-J, Fan T, Tsou E-Y, Tiu C. An effective mixing for lithium ion battery slurries. Adv Chem Eng Sci. 2014;04(4):515-28.
Mitali J, Dhinakaran S, Mohamad AA. Energy storage systems: A review. Energy Storage Sav. 2022;1(3):166-216.
Yadlapalli RT, Alla RR, Kandipati R, Kotapati A. Super capacitors for energy storage: Progress, applications and challenges. J Energy Storage. 2022;49:104194.
Lang X, Hirata A, Fujita T, Chen M. Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors. Nat Nanotechnol. 2011;6(4):232-6.
Wang G, Zhang L, Zhang J. A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev. 2012;41(2):797-828.
Gao X, Zu L, Cai X, Li C, Lian H, Liu Y et al. High performance of supercapacitor from PEDOT:PSS Electrode and redox iodide ion electrolyte. Nanomaterials (Basel). 2018;8(5):335.
Loganathan NN, Perumal V, Pandian BR, Atchudan R, Edison TNJI, Ovinis M. Recent studies of polymeric materials for supercapacitor development. J Energy Storage. 2022;49:104149.
Han J, Jang G-H, Kim DK, Kim JY, Shin JW, Hwang C-S et al. Dual-function electrochromic supercapacitor with graphene electrode. Int J Energy Res. 2022;46(8):10822-32.
Huang H, Zhao Y, Cong T, Li C, Wen N, Zuo X et al. Flexible and alternately layered high-loading film electrode based on 3D carbon nanocoils and PEDOT:PSS for high-energy-density supercapacitor. Adv Funct Mater. 2022;32(22):2110777.
Faruk O, Adak B. Recent advances in PEDOT:PSS Integrated Graphene and MXene-based composites for electrochemical supercapacitor applications. Synth Met. 2023;297:117384.
Salleh NA, Kheawhom S, Ashrina A Hamid N, Rahiman W, Mohamad AA. Electrode polymer binders for supercapacitor applications: a review. J Mater Res Technol. 2023;23:3470-91.
Yin HE, Lee CF, Chiu WY. Preparation of thermally curable conductive films PEDOT:P(SS-NMA) and their performances on weather stability and water resistance. Polymer. 2011;52(22): 5065-74.
Peng C, Snook GA, Fray DJ, Shaffer MSP, Chen GZ. Carbon nanotube stabilised emulsions for electrochemical synthesis of porous nanocomposite coatings of poly[3,4-ethylene-dioxythio-phene]. Chem Commun (Camb). 2006;(44):4629-31.
Randriamahazaka H, Plesse C, Teyssié D, Chevrot C. Ions Transfer Mechanisms during the Electrochemical Oxidation of poly[3,4-ethylenedioxythio-phene] in 1-ethyl-3-methylimidazolium bis-((trifluoromethyl)sulfonyl)amide Ionic Liquid. Electrochem Commun. 2004;6(3): 299-305.
White AM, Slade RCT. Electrochemically and vapour grown electrode coatings of poly(3,4-ethylenedixoythiophene) doped with heteropolyacids. Electrochim Acta. 2004;49(6):861-5.
Nithya VD. A review on holey graphene electrode for supercapacitor. J Energy Storage. 2021;44:103380.
Hu Z, Zhang J, Hao Z, Zhao Y. Influence od doped PEDOT:PSS on the performance of polymer solar cells. Sol Energy Mater Sol Cells. 2011;95(10):2763-7.
Cai W, Ma X, Guo J, Peng X, Zhang S, Qiu Z et al. Preparation and Performance of a Transparent poly(3,4-ethylene dioxythiophene)-poly(p-styrene sulfonate-co-acrylic acid sodium) Film with a High Stability and water Resistance. J Appl Polym Sci. 2017;134(31):45163.
Yano H, Kudo K, Marumo K, Okuzaki H. Fully Soluble Self-Doped poly(3,4-ethylenedioxythiophene) with an Electrical Conductivity greater than 1000 S cm-1. Sci Adv. 2019;5(4):eaav9492.
Hwang KH, Seo HJ, Nam SH, Boo JH. Preparation of gold nanorods using 1,2,4-trihydroxybenzene as a reducing agent. Nanosci Nanotechnol. 2015;15:10.
Shen L, Seo GU, Eun HJ, Prem P, Yoon SE, Kim JH et al. Synthesis and Charaterization of PEDOT:PSS-co-TF for enhancing detection performances of organic photodetectors. J Mater Chem C. 2023;11(21):7010-8.
Heuer HW, Wehrmann R, Kirchmeyer S. Electrochromic Wihdow Based on Conducting poly(3,4-ethylenedioxythio-phene)-poly(styrene sulfonate). Adv Funct Mater. 2002;12(2):89-94.
Li L, Li X, Shen Y, Chen X, Jiang L. ’Hydrophobicity and Corrosion Resistance of Waterborne Fluorinated Acrylate/Silica Nanocomposite Coatings’, e-polymers. 2021;21:779.
Park NY, Jeong GS, Yu YJ, Jung YC, Lee JH, Seo JH et al. Photovoltaic device application of a hydroquinone-modified conductive polymer and dual-functional molecular si surface passivation technology. Polymers. 2022;14(3):478.