Determination of the Concentrations of Heavy Metals in Borehole Water near Refuse Dump Sites around the University of Cross River State (UNICROSS) Calabar, Nigeria

Nwuyi Okori Sam-Uket

Department of Animal and Environmental Biology, Faculty of Biological Sciences, University of Cross River State, Calabar, Nigeria.

Elvis Monfung Ayim *

Department of Animal and Environmental Biology, Faculty of Biological Sciences, University of Cross River State, Calabar, Nigeria.

Samuel Monday Ameh

Department of Biology, Faculty of Science, Confluence University of Science and Technology, Osara, Kogi State, Nigeria.

Muhammed Haruna Isah

Department of Biology, Faculty of Science, Confluence University of Science and Technology, Osara, Kogi State, Nigeria.

*Author to whom correspondence should be addressed.


Abstract

The contamination of groundwater from the infiltration of leachates into aquifers and health risks on residents drinking from boreholes around dumpsites informed this study on the levels of heavy metals in the boreholes around the University of Cross River State (UNICROSS) dumpsite. Borehole water samples were aseptically collected from 3 boreholes at 50, 80, and 200 meters respectively from the dumpsite into a one-liter sampling bottle and preserved in an ice chest. The samples were then analyzed for heavy metals using Atomic Absorption Spectrophotometer. The values obtained were compared with WHO permissible standards for drinking water. The mean concentrations of Pb (0.614 ± 0.008), Cd (0.399 ± 0.053), As (0.023 ± 0.002), and Co (0.002 ± 0.001 mg/l) in the borehole water were significantly higher than WHO permissible limits, while the concentrations of Cr (0.002 ± 0.001) and Ni (0.056 ± 0.004) were significantly lower than the WHO permissible limits. The increasing trend of heavy metals in the borehole water was Cr = Co < As < Ni < Cd <Pb. Due to the health risks associated with drinking water contaminated with heavy metals, we recommend that Government should relocate the dumpsite far away from its current location.

Keywords: Dump sites, borehole, heavy metals, solid waste


How to Cite

Sam-Uket, N. O., Ayim, E. M., Ameh , S. M., & Isah, M. H. (2023). Determination of the Concentrations of Heavy Metals in Borehole Water near Refuse Dump Sites around the University of Cross River State (UNICROSS) Calabar, Nigeria . Chemical Science International Journal, 32(5), 26–32. https://doi.org/10.9734/CSJI/2023/v32i5857

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References

Onweluzo JC, Akuagbazie CA. Assessment of the quality of bottled and sachet water sold in Nsukka town. Agro-Science Journal of Tropical Agriculture, Food, Environment and Extension. 2010; 9(2):104–110.

Okonko IO, Ogunjobi AA, Adejoye AD, Ogunnusi TA, Olasogba MC. Comparative studies and microbial risk assessment of different water samples used for processing frozen sea foods in Ijora-olopa, Lagos State, Nigeria. African Journal of Biotechnology. 2008;7(16):2902-2907.

Tiimub BM, Sarkodie PA, Monney A, Maxwell O. Heavy Metal Contamination of Soil by Quarry Dust at Asonomaso in the Ashanti Region of Ghana. Chemistry and Materials Research. 2015; 7:42-50.

Shittu OB, Olaotan JO, Amusa TS. Physicochemical and bacteriological analysis of water used for drinking and swimming purposes in Abeokuta, Nigeria. African Journal of Biomedical Research. 2008;2:285-290.

Umeh CN, Okorie OI, Emesiani GA. Towards the provision of safe drinking water: The bacteriological quality and safety of sachet water in Awka, Anambra State. In: the Book of Abstract of the 29th Annual Conference & General Meeting on Microbes As Agents of Sustainable Development, organized by Nigerian Society for Microbiology (NSM), University of Agriculture, Abeokuta. 2005;22.

Hughes JM, Koplan JP. Saving Lives through Global Safe Water. Journal of Emerging Infectious Diseases. 2012; 11(10):1636-1637.

Chandra S, Singh A, Tomar PK. Assessment of Water Quality Values in Porur Lake Chennai, Hussain Sagar Hyderabad and Vihar Lake Mumbai, India. ChemSci Trans. 2012;1(3):508-515.

Arisi OI, Nnachi EE, Igwe OE, Obasi NP. Evaluation of pollution status of heavy metals in the groundwater system around open dumpsites in Abakaliki urban, Southeastern Nigeria. African Journal of Environmental Science and Technology. 2015;9(7):600-609.

Udofia UU, Udiba UU, Udofia LE, Ezike NN, Udiba SU. Assessment of the impact of solid waste dumps on ground water quality, Calabar Municipality, Nigeria. Journal of advance research in Biology and pharmacy Research. 2016;1(4):18–34.

Udiba UU, Anyanwu S, Gauje B, Dawaki SI, Oddy-Obi IC, Agboun TDT. Toxicity Potential of Allium cepa L. as a Bioindicator of Heavy Metal Pollution Status of River Galma Basin Around Dakace Industrial Layout, Zaria, Nigeria. International Journal of Biological Sciences and Applications. 2015;6(2):76-85.

Obiora SC, Chukwu A, Davies TC. Heavy metals and health risk assessment of arable soils and food crops around Pb-Zn mining localities in Enyigba, Southeastern Nigeria. Journal of African Earth Sciences. 2016;116:182-189.

Obialor PN, Ayim EM. Ecological studies of the spatial and temporal distribution of phytoplankton at high tide within the cross river estuary, south-eastern Nigeria. Global Scientific Journals. 2021;9(7):999– 1011.

Monechot WO. Leachate, groundwater, surface stream, treated water and soil characteristics of the vicinity of a municipal solid waste dumpsite at Uyo metropolis, Akwa – Ibom state, Nigeria. A project submitted in partial fulfillment of the requirement for the award of the Master of science degree (MSC) in analytical chemistry in the Department of pure and industrial chemistry, Faculty of Physical Sciences, University of Nigeria Nsukka; 2009.

American Public Health Associated (APHA). Standard method for examination of water and waste water, 20th Ed. American Public Health Associated Inc, New York; 1998.

American Water Work Associated (AWWA). Research Foundation, Bacterial examination of water. West Quincy Avenue Denver. 1993;81-85.

El-Sayed AE, El-Ayyat MS, Nasr E, Khater ZZK. Assessment of heavy metals in water sediment and fish tissues, from Sharkia province. Egyptian Journal of Aquatic Biology and Fisheries. 2011;15(2):125–144.

Taylor R, Allen A. Waste disposal and landfill: Potential hazards and information needs. In O. Schmoll, G. Howard, J. Chilton and I. Chorus (Eds). Protecting Groundwater for Health: Managing the of Drinking-water Sources. London: IWA Publishing Quality. 2006;55.

Salawu K, Owolarafe TA, Barau MM, Lawal TA, Abubakar MA, Fadilu M, Nwachukwu FC. Determination of Selected Heavy Metals in Seasonal River in Maru Town, Zamfara State, Nigeria. Journal of Environment and Earth Science. 2014;4:11–14.

Eni DI, Ubi AE, Digha N. Vulnerability Assessment of Boreholes Located Close to Lemna Landfill in Calabar Metropolis, Nigeria. International Journal of Physical and Human Geography. 2014;2(2):6-15.

Alonge DO. Textbook of meat hygiene in the Tropics. lbadan, Nigeria: Framcoe Publishers. 1991;121.

Afolayan OS, Ogundele FO, Odewumi SG. Hydrological implication of solid waste disposal on groundwater quality in Urbanized Area of Lagos State, Nigeria, International Journal of Applied Science and Technology. 2012;2(5):74-82.

Oni AA, Ossai AW, Lawal TK. Macro-faunal diversity of a contaminated dumpsite in Ibadan, Nigeria. Elixir Bio Diver. 2010;39(1):4905.

Udosen ED, Benson NU, Essien JP, Ebong GA. Concentration of heavy metals in waste dumpsites. International Journal of Soil Science. 2006;23:91-101.

Luter L, Akaahan TJ, Simon A. Heavy metals in soils of auto-mecahnic shops and refuse dumpsites in Makurdi. Journal Applied Science Environment. 2011;15(1):207-210.

Akpabio JJ, Ekpo FE. Physico-Chemical and Heavy metals quality assessment of borehole waterin different residential areas of Uyo Metropolis: A Case Study of G.R.A. and Low Income Residential Areas. International Journal of Science and Research. 2013;4(2):670–674.

Ivon EA, Joseph AP, Andem AB, Otong BE, Ebari SE. Evaluation of Emerging threats of contaminants in boreholes along Ikot Effanga dumpsite, Calabar Municipality Nigeria. Archives of Current Research International. 2017;9(3):1-12.

Jhamnani B, Singh SK. Groundwater Management through correlation studies among various physicochemical parameters. International Journal of Environmental Science. 2009;1(2):253-259.

Eni DV, Obiefuna J, Oko C, Ekwok I. Impact of urbanization on sub surface water quality in Calabar municipality, Nigeria. International Journal of Humanities and Social Sciences. 2011;1(10):167-172.

World Health Organisation (WHO). Protecting Groundwater for Health: Managing the Quality of Drinking-water Sources. Edited by O. Schmoll, G. Howard, J. Chilton and I. Chorus. IWA Publishing, London, UK. 2006;120.